I understand you would like to scan multipage documents to a single pdf file using your hp envy 4500 yes this is very possible.
Hp envy 4500 how to place sheet glass.
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Loading paper and envelopes for hp envy 4500 and hp deskjet ink advantage 3540 e all in one printer series introduction this document describes how to load plain paper photo paper and envelopes into the printer.
Make sure blank paper is loaded in the input tray for any fax reports that might print.
The printer scans the alignment page and completes the alignment.
Use the scanner glass.
Adjust the width guides to fit the item.
Align the stack of paper with the right and back edges of the tray.
Load label sheets so they properly feed into the printer.
Fan the label sheets being careful not to bend any corners or cause labels to separate from the backing sheet.
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Load the document face down on the scanner glass according to the guide on the edges.
Close the scanner lid and then press ok.
A preview of the scan displays by default.
Load 10 to 25 sheets of letter or a4 unused plain white paper into the tray.
Place the alignment page on the scanner glass.
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When you are using the hp software on your computer follow the steps below.
Place the test sheet behind the label sheet and then hold them up to a bright light to confirm the text is aligned and large enough.
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If your printer has an automatic document feeder adf place the document into the document feeder tray with the print side face up and the top edge going into the tray first.
You can load up to 35 sheets of paper in the adf.